MSDS for Vanadium (III) Bromide

Identification

Product Name: Vanadium (III) Bromide
Synonyms: Vanadium Tribromide
Chemical Formula: VBr₃
CAS Number: 13463-11-5
Manufacturer/Supplier: Specialty chemical distributors with laboratory and industrial supply chains
Recommended Use: Laboratory reagent, chemical synthesis, research applications
Contact Information: Emergency contact and company details with local and international emergency phone numbers

Hazard Identification

Classification: Acute toxicity (oral, dermal, inhalation), Skin corrosion, Eye damage, Specific Target Organ Toxicity
Signal Word: Danger
Hazard Statements: Harmful if swallowed, in contact with skin, or inhaled; Causes severe skin burns and eye damage;
Precautionary Statements: Avoid all unnecessary exposure. Do not breathe dust, particles, or fumes.
Pictograms: Corrosive symbol, Exclamation mark, Health hazard
Routes of Entry: Inhalation, skin, eyes, ingestion
Hazard Description: Irritant properties and corrosive potential can lead to inflammatory reactions in the respiratory tract, skin, and eyes. Ingestion risks include severe digestive tract burns and systemic toxicity. Dust may aggravate symptoms in those with pre-existing conditions.

Composition / Information on Ingredients

Chemical Name: Vanadium (III) Bromide
Common Name: VBr₃
Concentration: 100%
Impurities: Trace amounts of unreacted vanadium compounds or residual bromide salts
Molecular Weight: 274.65 g/mol

First Aid Measures

General Advice: Call poison center or doctor immediately in case of exposure; keep exposed individual calm and warm.
Inhalation: Remove to fresh air without delay; give oxygen if breathing is difficult. Seek prompt medical attention.
Skin Contact: Remove contaminated clothing. Wash affected area thoroughly with water for at least 15 minutes. Seek medical advice if irritation persists or burns develop.
Eye Contact: Rinse cautiously with plenty of clean water for several minutes, lifting upper and lower eyelids. Continue rinsing and obtain medical attention.
Ingestion: Rinse mouth with water if conscious; do not induce vomiting. Provide medical help quickly due to corrosive action on digestive tract.

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical powder, appropriate foam, or carbon dioxide. Water may not be effective on this compound and could react violently.
Hazardous Combustion Products: Formation of toxic and corrosive bromide fumes and vanadium oxides.
Precautions for Firefighters: Full protective gear and approved self-contained breathing apparatus required. Approach from upwind side. Remain at a safe distance.
Specific Hazards: Risk of toxic and irritating vapors released in fire conditions. Exposed containers may rupture due to pressure build-up.

Accidental Release Measures

Personal Precautions: Restrict access to the area. Put on appropriate personal protective equipment, including gloves, goggles, and a fitted respirator.
Environmental Precautions: Keep spills away from drains, watercourses, and soil. Prevent product from spreading.
Spill Cleanup Methods: Carefully sweep up the material using non-sparking tools. Place in a sealed, labeled container for proper disposal. Ensure adequate ventilation to disperse fumes.

Handling and Storage

Handling: Work in fume hood or well-ventilated space. Avoid contact with skin, eyes, and clothing. Do not breathe dust or fumes. Ensure containers remain tightly closed and are handled with care.
Storage Conditions: Store away from heat, open flames, and incompatible substances like strong oxidizers and moisture. Use tightly sealed, chemically resistant containers. Label storage area clearly, restrict access to trained personnel.
Incompatibilities: Water, strong oxidizing agents, acids, alkalis, organic combustibles

Exposure Controls and Personal Protection

Exposure Limits: No specific OSHA or ACGIH limits for vanadium (III) bromide; as vanadium compounds, follow recommended exposure control guidelines.
Engineering Controls: Use process enclosures and local exhaust ventilation to reduce airborne levels.
Personal Protective Equipment: Chemical-resistant gloves (nitrile or neoprene), safety goggles, lab coat, and closed footwear. For potential exposure, use a NIOSH-approved respirator.
Hygiene Measures: Wash thoroughly after handling. Remove contaminated clothing and launder before reuse.

Physical and Chemical Properties

Appearance: Dark green to black solid, crystalline powder
Odor: No characteristic odor
pH: Not applicable (insoluble in water)
Melting Point: 425°C
Boiling Point: Decomposes before boiling
Solubility: Decomposes in water, soluble in some organic solvents
Density: 4.87 g/cm³
Vapor Pressure: Negligible at room temperature
Flash Point: Not applicable
Evaporation Rate: Not volatile
Other Data: Highly reactive with strong oxidizers and humidity

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions in an inert, dry atmosphere.
Reactivity: Reacts with water and moisture, releasing hydrogen bromide gas.
Hazardous Decomposition Products: Vanadium oxides, hydrogen bromide
Incompatible Materials: Water, acids, strong oxidizing agents, alkalis
Polymerization: No hazardous polymerization expected
Conditions to Avoid: Humidity, exposure to air, thermal decomposition from heat

Toxicological Information

Acute Toxicity: Harmful by ingestion, inhalation, and dermal contact; irritation and burns to skin and mucous membranes.
Long-term Exposure: Repeated exposure may lead to lung, skin, and kidney effects due to vanadium accumulation.
Symptoms: Coughing, sore throat, shortness of breath, skin redness, eye burns, nausea, vomiting
Carcinogenicity: No classification by IARC, NTP, or OSHA for vanadium (III) bromide; other vanadium compounds classified as possibly carcinogenic.
Additional Data: Data is scarce for this particular compound, but risk profiles align with other vanadium salts and bromide compounds.

Ecological Information

Ecotoxicity: Harmful to aquatic organisms. Toxicity increases through bioaccumulation in plants and animals, leading to ecosystem disruption.
Persistence and Degradability: Not rapidly degradable in the environment. Can persist in soils and sediments.
Bioaccumulative Potential: Moderate to high bioaccumulation risk due to heavy metal content.
Mobility in Soil: Limited by low solubility but can migrate if released in acidic or saline conditions.
Other Environmental Hazards: Avoid release to waterways, wastewater, and natural habitats.

Disposal Considerations

Methods of Disposal: Collect residue and unused material for disposal at a licensed hazardous waste facility. Do not dump into sewer, water, or soil.
Packaging Disposal: Decontaminate and dispose of packaging as hazardous waste.
Precautions: Wear appropriate protection during collection and disposal. Follow local, national, and international regulations for heavy metal compounds.

Transport Information

UN Number: 3288
UN Proper Shipping Name: Toxic Solid, Inorganic, N.O.S. (Vanadium (III) Bromide)
Transport Hazard Class: 6.1 (Toxic substances)
Packing Group: II (medium danger)
Hazard Labels: Toxic
Environmental Hazards: Marine pollutant
Special Transport Precautions: Use sealed, corrosion-resistant packaging. Ensure containers will not be damaged in transit. Emergency procedures should be available during shipping.

Regulatory Information

Regulatory Status: Subject to handling, storage, and disposal regulations as a toxic and environmentally hazardous material under national and international chemical laws.
SARA Title III: Not specifically listed, but vanadium compounds are subject to reporting requirements for hazardous substances.
TSCA Inventory: Listed
REACH Status: Registration may be required in the EU for manufacturers or importers.
Other Regulatory: Local, state, and country-specific chemical safety laws govern sourcing, use, and waste management.