Material Safety Data Sheet: Vanadium Glycinate

Identification

Product Name: Vanadium Glycinate
Chemical Formula: C4H8N2O4V
Synonyms: Glycine vanadium complex, Bis(glycinato)oxovanadium(IV)
CAS Number: 62013-04-7
Recommended Use: Laboratory research, catalyst, nutritional studies (non-food use)
Supplier Details: Name, address, telephone, and email of supplier or manufacturer
Emergency Contact: Local emergency number or manufacturer emergency phone

Hazard Identification

GHS Classification: Acute toxicity (oral, dermal, inhalation), Eye irritation
Hazard Statements: Harmful if swallowed, Harmful if inhaled, Causes mild to moderate eye irritation, May cause allergic skin reaction
Pictograms: Exclamation mark
Signal Word: Warning
Precautionary Statements: Avoid breathing dust; Wash hands thoroughly after handling; Wear protective gloves; If in eyes, rinse with water; If ingested, seek medical help
Target Organs: Kidneys, liver
Chronic Health Effects: Possible impact on blood chemistry in prolonged exposure, especially in unprotected handling

Composition / Information on Ingredients

Substance: Vanadium Glycinate
Concentration: 98% minimum
Impurities: Glycine traces, sodium chloride, water content < 1%
CAS Number: 62013-04-7
EC Number: Not assigned

First Aid Measures

Inhalation: Move person to fresh air, keep at rest, monitor for signs of breathing difficulty, provide oxygen if needed
Ingestion: Rinse mouth, do not induce vomiting, seek immediate medical attention if large amounts swallowed, offer water orally
Skin Contact: Remove contaminated clothing, flush affected area with plenty of water and mild soap for at least 15 minutes
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses, continue rinsing, seek medical advice if irritation persists
General Advice: Consult a physician, show medical staff this sheet; offer symptomatic and supportive care only

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical powder, foam, carbon dioxide (CO2), water spray
Unsuitable Extinguishing Media: High-pressure water jet may spread powder
Fire Hazards: Non-flammable; burns may generate toxic vanadium oxides, nitrogen oxides, carbon oxides
Special Protective Equipment: Firefighters should use self-contained breathing apparatus and full protective gear
Other Information: Prevent runoff from entering drains, surface water, or groundwater

Accidental Release Measures

Personal Precautions: Evacuate area, avoid dust generation, use personal protective equipment such as gloves, masks, goggles
Environmental Precautions: Avoid release to soil, waterways, drains; inform relevant authorities if contamination has occurred
Cleanup Methods: Sweep up and place in secure, labeled container; avoid raising dust; ventilate area; wash spill location with water and detergent after removal
Disposal: Follow local regulations for chemical waste; consult licensed waste disposal contractor

Handling and Storage

Handling: Use only in well-ventilated areas, avoid contact with skin, eyes, and clothing, do not eat or smoke during handling, practice good industrial hygiene
Storage Conditions: Store in tightly closed container in cool, dry, well-ventilated area, keep away from incompatibles such as strong oxidizers and acids
Incompatible Materials: Acids, oxidizing agents, strong bases
Other Precautions: Keep out of reach of children, restrict untrained persons from access, inspect containers regularly for leaks or damage

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established threshold limit for vanadium glycinate; observe vanadium compound limits (OSHA PEL: 0.05 mg/m³ as vanadium)
Engineering Controls: Local exhaust ventilation, fume hood for laboratory use
Personal Protective Equipment: Nitrile gloves, chemical-resistant goggles, lab coat, dust mask or respirator (NIOSH approved)
Hygiene Measures: Wash hands before breaks and after finishing work, remove contaminated clothing immediately and launder before reuse

Physical and Chemical Properties

Appearance: Grey to blue crystalline powder
Odor: Odorless
Boiling Point: Not applicable
Melting Point: Decomposes above 200°C
Solubility: Soluble in water, slightly soluble in ethanol
pH (1% Solution): 5.5 to 7.0
Vapor Pressure: Not significant at ambient temperatures
Density: 1.9 – 2.1 g/cm³
Flash Point: Not flammable
Explosive Properties: Not explosive
Other Properties: Stable under normal storage and handling, decomposes on strong heating

Stability and Reactivity

Chemical Stability: Stable under recommended storage and handling conditions
Conditions to Avoid: High heat, strong acid or oxidizing environments
Hazardous Reactions: Contact with strong oxidizers releases toxic gases, reacts with acids to emit vanadium oxides
Decomposition Products: Vanadium oxides, carbon oxides, nitrogen oxides
Polymerization: Not expected under normal temperature and pressure

Toxicological Information

Acute Toxicity: Harmful if swallowed, inhaled or absorbed through skin
LD50 (Oral, Rat): No direct data; reference vanadium salts LD50 10–30 mg/kg
Skin Corrosion/Irritation: May cause mild to moderate irritation after prolonged contact
Eye Damage/Irritation: Causes irritation, redness, tearing
Respiratory Sensitization: Dust may trigger coughing, shortness of breath if inhaled
Chronic Effects: Potential kidney, liver, and blood effects after long-term exposure
Carcinogenicity: Not listed by IARC, NTP, or OSHA as a confirmed carcinogen
Other Health Effects: May cause oxidative stress and transient changes in glucose metabolism at toxic doses

Ecological Information

Aquatic Toxicity: Toxic to aquatic organisms; vanadium accumulates in sediment
Persistence and Degradability: Complex persists in environment, not easily degraded
Bioaccumulation: Vanadium has potential to bioaccumulate in aquatic food chains
Soil Mobility: Medium mobility; binds to soil particles but can leach under acidic conditions
Other Adverse Effects: Vanadium compounds linked to disruption of aquatic plants and lower invertebrates

Disposal Considerations

Waste Treatment Methods: Collect spills and residues, package in sealed containers, label appropriately
Disposal of Product: Incinerate in a controlled facility, landfilling allowed if in accordance with local regulations
Disposal of Contaminated Packaging: Rinse thoroughly, dispose as hazardous chemical waste
Precautions: Do not discharge to natural waters, soil, or public sewers
Legal Requirements: Disposal subject to federal, state, and local regulations

Transport Information

UN Number: None assigned for vanadium glycinate; refer to local conventions for vanadium compounds
DOT (US): Not regulated as hazardous for transport in original packaging
IMDG: Not classified as marine pollutant but restrict large volume shipments
Packing Group: Not assigned
Special Precautions for Transport: Securely close container, prevent spillage, protect from moisture
Other Information: Emergency schedules should be available during shipment into, within, or out of facilities

Regulatory Information

US TSCA: Not explicitly listed; vanadium compounds generally regulated
SARA Title III: Not listed in SARA 302, 304, or 313 for reporting
California Proposition 65: Vanadium and its compounds not listed but may be considered under some interpretations
OSHA: Regulated as hazardous chemical
REACH: Substance pre-registered under applicable guidelines
Other Regulatory Information: Local, state, and national laws may apply for handling, storage and environmental impact of vanadium complexes; consult relevant authorities